![]() Oxidizers include boron(III) oxide, silicon(IV) oxide, chromium(III) oxide (Cr 2O 3 + 2 Al → 2 Cr + Al 2O 3), manganese(IV) oxide, iron(III) oxide (Fe 2O 3 + 2 Al → 2 Fe + Al 2O 3), iron(II,III) oxide, copper(II) oxide, and lead(II,IV) oxide. Aluminum is common because of its high boiling point of 2,470 ☌. Fuels include aluminum, magnesium, titanium, zinc, silicon, and boron. Most varieties are not explosive but can create brief bursts of high temperature in a small area. When ignited by heat, thermite undergoes an exothermic redox (reduction–oxidation) reaction. Thermite is a pyrotechnic composition of metal powder, fuel and metal oxide. The runaway reaction made it possible to produce only small quantities of material. The oxide was heated with aluminum in a crucible placed in a furnace. The reaction is highly exothermic, but it has a high activation energy since strong interatomic bonds in the solids must be broken first. Beketov executed the reduction of some metals from their oxides by means of aluminum at high temperatures, thus laying the basis of the aluminothermic process, which is now widely used in metallurgy. ![]() 14) at the University of Kharkov in Ukraine. The aluminothermic reduction (Aluminothermy) started from the experiments of the renowned Russian physical chemist Nikolay Nikolayevich Beketov (Hикoлaй Hикoлaeвич Бeкeтoв) (1827–1911) (Fig. The interactive Ellingham diagram is a teaching and learning tool, which can be used to obtain a variety of valuable thermodynamic information pertaining to a wide range of reactions. Thus, processes that are predicted to be favorable by the Ellingham diagram can still be slow. The analysis is thermodynamic in nature, and ignores reaction kinetics. The diagrams are useful in predicting the conditions under which an ore will be reduced to its metal. In metallurgy, the Ellingham diagram is used to predict the equilibrium temperature between a metal, its oxide and oxygen and-by extension-reactions of a metal with sulfur, nitrogen, and other non-metals. The diagrams were first constructed by the British physical chemist Harold Johann Thomas Ellingham (1897–1975) in 1944. This analysis is usually used to evaluate the ease of reduction of metal oxides and sulfides. An Ellingham diagram is a graph showing the temperature dependence of compounds’ stability. The ability of metals to participate in thermic reactions can also be predicted from Ellingham diagrams. ![]() This effect was used by Theodore Harold ‘Ted’ Maiman (1927–2007) in 1960 to make the first successful laser, based on ruby. When the optical arrangement is such that the emission is stimulated by 694-nm photons reflecting back and forth between two mirrors, the emission grows strongly in intensity. The picture of a beautiful ruby is presented in Fig. When yellow-green light is absorbed, it is transmitted as red. This crystallographic arrangement results in light absorption in the yellow-green region of the spectrum. The red color is caused mainly by the presence of Cr III. Each Al III ion (and thus each Cr III ion) in the corundum crystal is surrounded by six oxide ions in a distorted octahedral coordination (Fig. Ruby is considered one of the four precious stones, together with sapphire, emerald and diamond. Rubies have a hardness of 9.0 on the Mohs scale of mineral hardness. ![]() Ruby’s name comes from ruber, Latin for red. A ruby is a pink to blood-red colored gemstone, a variety of the mineral corundum (α-alumina), Al 2O 3, in which a small fraction of Al III is replaced by Cr III. ![]()
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![]() You Found it! Love This Mug: The Cute and Funny Coffee Mug She or He WILL LOVE! Novelty Coffee Mugs and Gifts - Whether this is a gift for a coffee or tea-loving friend or family member, or if you're purchasing it for yourself. ✔ SATISFACTION GUARANTEED: We know you will love it!Ībout Retirement Gifts For Women, Men - Gag Gifts For ✔ HIGH QUALITY 11 OZ ceramic mug that's printed on both sides and is both microwave and dishwasher safe, so don't worry about it fading. ✔ Retirement Gag Gifts.because every retired firefighter, police officer, nurse, teacher, bus driver, boss, postal worker, mailman, dog groomer, librarian, realtor/realestate agent, hairdresser, veterinarian, dentist, US Army, Navy, Air Force, Marine, judge, sheriff. ✔ This funny retirement mug, "I worked my whole life for this mug" is perfect because we all love hilarious retirement gifts! Women and men, alike will enjoy their coffee or tea from this humorous mug with a touch of sarcasm! ✔ BEWARE OF FAKE SELLERS: Connies3Ms is the only authorized seller of this mug! 2018 Retirement Gifts for Women and Men alike are best when they will remind them of your friendship, over and over! It's the PERFECT GIFT for any coworker, dad, mom, friend who is a coffee or tea lover! He also plans to do some volunteer work.Retirement Gifts for Women, Men - Gag Gifts for Features A 92-year-old neighbor who moved to Colorado some years ago called during the party to wish Burns a happy retirement.īurns, who lives in Palo Alto with his wife, is planning to rehab himself for a year after decades of nicks, bumps and bruises accumulated from delivering mail. Post Office.īurns even received well wishes from those long gone from southern Cupertino. The get-together had a Presidents Day theme that conveniently matched the red, white and blue colors of the U.S. Burns received gifts including a number of gag gifts and bakery treats. Burns helped deliver the packages for the neighborhood, Judy said.įliers were passed around the neighborhood to drum up interest in the retirement party. Many years ago, the neighborhood rallied to send care packages to servicemen in the Gulf War. “I remember we did a remodel of our kitchen and Mike would pop his head in to ask how it was going. ![]() “We had that kind of personal relationship,” Judy said. “We’re the old standbys that have been here for a longtime,” Judy said.īurns even had his tax preparation done by Al. ![]() The Mounses estimate the median age of party attendees was 70. The party had 26 attendees, including Burns’ son who made a surprise drive up from the Fresno area for the party. “I guess in a word, it was awesome that these people think that much of you to do something like this.” I had a wonderful time on that route for many years,” Burns told the Courier. “It was kind of like going back to a family reunion. Stelling Road, Aster Lane, Normandy Way and portions of S. Since roughly 1985, Burns delivered mail for the Monta Vista post office to streets including S. 16 at Judy and Al and Mouns’ home on Waterford Drive to say “thanks” to Mike Burns, the neighborhood’s longtime mailman, who is set to retire. Residents in a neighborhood at Cupertino’s southernmost boundary decided it was time to deliver well wishes to the man who for a quarter century delivered notes to them just about every day of the week. ![]() ![]() Also, it should be easier to find e-mail links that you can link to to send files to friends out side of the Dropbox network.ĭropbox for Mac is a great idea in theory but in reality, it works quite slowly although it's useful for the sharing of really big files.ĭropbox -Fix a bug where the Dropbox folder would not go back to the same place on relink for dual account and DfB users.Fix a bug where Dropbox wouldn't work if your DfB team name had unicode characters.Fix incorrect text on setup wizard panel Changesĭropbox -Fix a bug where the Dropbox folder would not go back to the same place on relink for dual account and DfB users.Fix a bug where Dropbox wouldn't work if your DfB team name had unicode characters. Timo Josten’s Dropshare 4 ( a secure file sharing tool developed exclusively for Mac OS X 10.9 and higher, has been revved to version 4, which adds a revamped user interface. The problem is that since Dropbox for Mac synchronizes with your files, it slows down your system considerably and dropping files into it can be painfully slow. pClouds latest feature Branded links allows you to customize download links with your brands. Compare features, ratings, user reviews, pricing, and more from Dropshare competitors and alternatives in order to make an informed decision for your business. Worth to mention, Dropshare works perfectly well in IPv6 environments. SourceForge ranks the best alternatives to Dropshare in 2023. ![]() Find helpful reviews and comments, and compare the pros and cons of Dropshare 5. By doing so, you can perfectly use the tools Mac OS X provides to create e.g. Dropshare 5 was rated 4.77 out of 5 based on 13 reviews from actual users. Dropshare is a menu bar app that enables you to drag & drop upload files, screenshots and even directories to your own server to share them with anyone you like. Dropshare introduces itself to the Mac OS X Services Menu. Dropshare is your very own secure file sharing tool. A public folder lets you share files with other people, whether or not they registered with the service offered by Dropbox. If enabled, Dropshare automatically converts Markdown files to HTML. 3.7 39 Ratings Free Offers In-App Purchases Screenshots iPhone iPad Dropshare is an easy-to-use app for iOS that allows you to quickly share single files via download URL. For 9.99/mo, use Dropshare plus over 200 other apps. ![]() Setapp is a subscription service for Mac and iOS apps. We live data protection by default - Dropshare Cloud is built in Germany and hosted in the European Union. FreeScaler: a free and open source tool used to upscale low-res images using advanced AI models, available on the Mac App Store. All your uploads are delivered via TLS transport encryption by default, even with your own domain. For both there are many options, I think it can‘t be too difficult to automate the link between. Alternatively, you can access files from any Web browser and download the files hosted onto your account. What do you dislike about Dropshare Maybe use two tools: one for the screenshot and one for the uploading. ![]() ![]() And when you're finished, toss it, hide it, or Burn After Writing. This is not a diary, and there is no posting required. Whether you are going through the ups and downs of growing up, or know a few young people who are, you will flourish by finding free expression-even if through a few tears! Push your limits, reflect on your past, present, and future, and create a secret book that's about you, and just for you. Imagine instead of publicly declaring your feelings for others, you privately declared your feelings for yourself? Help your heart by turning off the comments and muting the accounts that drive you into jealousy for a few moments a night. Through incisive questions and thought experiments, this journal helps you learn new things while letting others go. Burn After Writing allows you to spend less time scrolling and more time self-reflecting. The last thing you should do is share it. Jones meant the book to be kept private: upon its completion, you could bin it, hide it away, or do exactly as the title suggests. Instagram, WhatsApp, Snapchat, TikTok, VSCO, YouTube.the world has not only become one giant feed, but also one giant confessional. First published in 2014 by British graphic designer Sharon Jones, Burn After Writing was intended to reverse the trend of using social media as one giant confessional. ![]() The national bestseller "This book has made me laugh and cry, filled me with joy, and inspired me." - TikTok user camrynbanks The phenomenally popular secret journal filled with private prompts for personal reflection, self-exploration, and fueling creativity. ![]() ![]() That is why we provide collections of quilting patterns that are organized by type. If you are a quilter who loves the art of quilting, you might know exactly what kind of quilt you want to piece together next. We are constantly updating these collections and this page, so check back every once in a while to see if there is something new that might strike your fancy! ![]() Just scroll on down until you find the pattern you know you want. Whether you came here looking for quilting patterns for baby quilts, full quilt patterns, free block patterns, or anything else, there is probably a collection below that you are going to enjoy. 900+ Free Quilting Patterns is comprised of some of our most popular collections of quilt patterns, making it extra easy for quilters to find what they are looking for amongst our long, long list of stunning projects. This is exactly why we have compiled this giant list of patterns. We totally understand that it can be hard to choose as you look at quilting pattern after free quilting pattern. Even the editors come across quilts they have never seen before at least once a day! All of these quilt patterns are an amazing resource, but sometimes it can be hard to decide what quilt to make! We have beginner quilting patterns, free patterns for experienced quilters, and everything in between. From cute baby quilt patterns to quick quilt patterns made from pre-cuts, our selection is insanely extensive. Here at FaveQuilts, we have literally hundreds of free patterns and quilt project ideas for you to check out. ![]() ![]() You will be required to provide to Barrette Outdoor Living pictures and/or samples The defect and you must show original proof of purchase receipt. Barrette Outdoor Living requires written notice or phone call within thirty (30) days of discovering Website or call the phone number listed below. What Barrette Outdoor Living does to remedy the problem: Should your Barrette Outdoor Living product prove defective under warranty, visit the This limited warrantyĭoes not cover costs of removal or disposal of product, or reinstallation of replacement product. ![]() ![]() Is installed pollutants and chemicals including salt water, pool and ice removal chemicals and staining from foreign substances. Hurricane, tornado, high winds or other casualty or act of God movements, distortion, collapse or settling of ground or structure on which the railing What this warranty does not cover: This limited warranty does not cover damage resulting from: a change in color due to a build-up of surface moldĪnd mildew, misuse, abuse, improper storage or handling, improper installation, other vinyl products and accessories that are not manufactured byīarrette Outdoor Living, or manufactured for specific use in vinyl railing applications impact of foreign objects, fire, earthquake, flood, lightning, hail, Degrees of fading vary depending on geographical location,Īir pollution, exposure and other factors. Standard variation determined by Delta E color measurement, not to exceed Delta 5). *After prolonged exposure to outdoor environments, all products will experience some gradual fading over time and is considered normal (up to a Under normal atmosphere and weather conditions structural damage due to weather influences, fungal decay or wood boring insects. This limited warranty is valid beginning on the date of Product purchase.īarrette Outdoor Living warrants the Product against peeling, flaking, rotting, chipping, cracking, rusting, blistering, or abnormal discoloration/fading* What is covered: Barrette Outdoor Living warrants that its vinyl railing products (“Product”) will be free from defects in material and workmanship for The warranty period will be twenty (20) years following the original date of Product purchase. Partnerships, trusts, religious organizations, schools, condominiums, homeowner associations, cooperative housing arrangements and apartmentīuildings. A twenty (20) year limited warranty covers any other type of building or property including those owned by corporations, governmental agencies,.Individual transferee as specified herein. This limited warranty extends to the original purchaser and one (1) The limited lifetime warranty covers single-family residential properties only.Color matched cap and divider molding available. ![]() With the look of wood, but without needing to be sanded, stained, or repainted. Made with rigid, high-density polyethylene for strength and durability to withstand harsh weather conditions. Lattice screws are color matched to the lattice colors so they blend seamlessly into your install! STRONG AND DURABLE: Lattice installs easily using our lattice dividers to connect adjacent panels, and our lattice end cap for a clean, finished end. 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Courtship includes chases, gifting sticks or blades of grass to a significant other and males putting on displays by raising and lowering wings, tail wagging and bowing.A roadrunner can run only 15 mph - or a little faster if sprinting - meaning it could not actually outrun Wile E. You can listen to the Audubon's recordings of the roadrunner's song here.Roadrunners may mate for life. ![]() Its song can sometimes be mistaken for dove coos or dog-like whines. Roadrunners are a part of the Cuckoo family. to truckers in need of rest with technology Our director shares his thoughts. Here are five facts to know about the majestic bird. A map displaying live traffic information in the project area and on nearby. ![]() A roadrunner's diet consists of the occasional cactus fruit or seed, but mostly of smaller birds, lizards, mice, bugs and even rattlesnakes. According to the National Audubon Society, roadrunners are common in brushlands and deserts throughout the Southwestern United States and in Mexico. 18-The roadrunner - more specifically the greater roadrunner, scientific name Geococcyx californianus - was declared New Mexico's state bird in 1949. ![]() ![]() MacX Video Converter has an in-built Youtube video downloader which can download 3D, 4k as well as Blu-ray It is easy to Download YouTube HD video on Mac free now. Converting an MKV video(2.23 h,8GB) to MP4 takes less than 3 minutes. MacX Video Converter has the best video compression rates for Mac without any quality loss. If you love editing videos, you can convert videos for editing via iMovies, Final Cut Pro. 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This software will be a life-saver for those who need to edit videos too. Moreover, you will get rid of those annoying advertisements form YouTube once you download the videos. MacX is the only trusted IDE for videos which can save your time wasted in converting your favorite videos. When it comes to downloading YouTube videos, converting them to the desired format and compressing them, MacX Video Converter Pro comes to our rescue. To enjoy the best video playback without ads, we can download these videos offline. The worst part about YouTube is ads which seems so annoying at times to us. ![]() YouTube is one of the best video sharing platforms with billions of users worldwide. ![]() ![]() They previously starred in Ted Demme‘s 1999 comedy Life and in Murphy’s 1992 comedy Boomerang. Meanwhile, Jasmin is the daughter of Martin and his ex-wife Patricia Southall.Īlthough the two legendary comedians have not commented on their kids dating, the now-public relationship could offer a reason for Eddie and Martin to work together again. “Head over heels in LOVE with YOU,” he captioned the selfie, adding the hashtags “#myotherhalf,” “#equallyyoked” and “#iloveyou.”įor those who may not recall, Eric is the firstborn son of Eddie and his former girlfriend Paulette McNeely. Jasmin’s sweet post comes just weeks after Eric declared his love for her in an Instagram post. Cheers to many more blessings, laughs, and beautiful memories! I love you so much!!” “I’m so incredibly blessed to know you, to love you, and to have you by my side. ![]() ![]() Over the weekend, Jasmin, 25, shared a photo of her and Eric with a loving caption in celebration of his 32nd birthday. Magazine Innovators Awards )Įddie Murphy‘s eldest son, Eric, and Martin Lawrence‘s oldest daughter, Jasmin, have made their relationship Instagram official. They better watch out.Lars Niki/Getty Images for WSJ. She’s at that age where she’s liking boys, she thinks boys are cute, and when they come to the house I will have that face on. “My oldest is 15 and she’s a straight-A student. “I’ve got good girls,” he told Metro UK in 2011. They reunited for the 1999 comedy Life, in which two strangers who are wrongfully convicted become friends in prison.Īt time of press, neither actor have commented on their kids’ relationship, but Lawrence has opened up about fatherhood and his daughters dating in the past. ![]() The first time was in 1992 for the rom-com Boomerang alongside Halle Berry and Robin Givens. Lawrence and Murphy have both had pretty epic careers, but have only starred together on the big screen twice. ericmurphy777/Instagram Jasmin revealed in January that she and. Jasmin has two half-sisters, Ilyanna and Amara, whom Lawrence shares with his ex-wife Shamicka Gibbs. Martin Lawrence’s daughter Jasmin (R) was the lucky recipient of the bouquet at Eddie Murphy’s daughter Bria (L)’s wedding. Lawrence had her with his ex-wife, Patricia Southall, in 1996. Jasmin, a Duke University grad and actor, is also the eldest in her family. Murphy shares his other children with Nicole Murphy, Tamara Hood and Melanie Brown (a.k.a. He and Paulette McNeely had Eric in 1989. Murphy has 10 children, Eric being the oldest, and his youngest being two years old. At the time, Arsenio Hall weighed in with three clapping hand emojis, showing his approval of the coupling. ![]() Two weeks ago Eric, a writer and voice actor, posted a photo of himself and Jasmin together with the caption, “Head over heels in LOVE with YOU.” He also used the hashtags #myotherhalf and #Iloveyou. This isn’t the first time the couple has shared photos of themselves, however. I LOVE YOU,” he responded with a handful of heart emojis. “Cheers to many more blessings, laughs, and beautiful memories! I love you so much!!”Įric, 32, thanked Jasmin in the comments. “Happy birthday, my love! I'm so incredibly blessed to know you, to love you, and to have you by my side,” the 25-year old wrote. On July 10, Jasmin wished Eric a happy birthday on the social media platform, revealing in the caption that they’re dating. Thanks to an Instagram post over the weekend, fans learned that Eddie Murphy’s son, Eric, and Martin Lawrence’s daughter, Jasmin, are a couple. Two of Hollywood’s most iconic actors now have something else in common: their kids are head over heels in love. ![]() ![]() ![]() However, despite their aggression towards predators, farmers find that these birds are friendly towards their human owners. ![]() Today, Liege Fighter roosters are more commonly utilized to protect hens due to their aggressive behavior. One of the main reasons behind their hefty price tag is their giant size. This breed originates from Belgium and is classified as a game fowl. The Liege Fighter’s feathers are also stunning. Their impressive appearance is further accentuated by their exceptionally large feet, which rival those of a turkey. These chickens can grow to twice the size of American game fowl, with their weight primarily composed of muscle. Unfortunately, this chicken breed was historically famous for cockfighting due to its combative nature. The Liege Fighter, true to its name, is not only one of the most expensive breeds but is also known for its aggression. If you come across one, be prepared to pay up to $250. Pullets (young hens), in particular, are in high demand and often difficult to find for purchase. One of the main factors contributing to their steep price is their rarity. Thanks to recent imports, Deathlayer chickens are now available in the United States. In terms of diet, the Deathlayer enjoys feasting on Japanese beetles, watermelons, and mealworms. With its tight cushion comb, stunning iridescent greens and purples in its majestic tail, black feathers, and striking black doll eyes, it easily stands out among the most beautiful chickens in the world. When it comes to appearance, Deathlayer is truly captivating. Originally hailing from Germany, Deathlayers are known for their high yield. This makes them highly productive and a popular choice for those seeking laying hens. The Deathlayer is known for its exceptional egg-laying ability, with hens laying eggs until their very last day, unlike most other breeds that stop laying after a maximum of three years. Unlike other chicken breeds, Deathlayer hens lay eggs until their last breath!©DerBauer2310 / CC BY-SA 4.0 – License They are not far behind Ayam Cemani and are priced at $2,000 for a single pullet, making them the second most expensive chicken breed in the world! 3. Their slow growth rate also contributes to their high price. They are susceptible to changes in climate and require more care compared to most other chicken breeds. Once reserved for royalty and ceremonial offerings, Dong Tao chickens are now served in upscale restaurants catering to the wealthy.ĭespite their popularity, Dong Tao chickens are incredibly rare. In Vietnam, Dong Tao chicken feet and legs are considered a prized delicacy, further contributing to their exclusivity. With its enlarged, scaly feet resembling something out of a legend, this rare breed is often referred to as the Dragon chicken. One look at the Dong Tao chicken, and you’ll immediately understand why it’s so distinctive. However, the demand for these chickens is so high that breeders struggle to meet the demand. Dong Tao - $2,000Ī single Dong Tao pullet can cost up to $2,000 or more!©Hoang Quoc Phuong/ĭong Tao, originating from Vietnam, is renowned for having the most delectable meat among all chicken breeds. Additionally, Ayam Cemani eggs are thought to provide a range of health benefits.įor a healthy pair of this breed, expect to pay a whopping $5,000 (or $2,500 each)!ĭespite their popularity among backyard chicken enthusiasts, the Ayam Cemani breed has yet to be officially recognized by the American Poultry Association. This makes it an excellent choice for individuals looking to boost their protein intake and maintain a healthy diet. The meat of Ayam Cemani chickens is well-regarded for being rich in protein and low in fat compared to other chicken breeds. However, they do require a higher protein diet than most other chicken breeds due to their rapid growth rate.īesides their taste and scarcity, Ayam Cemani chickens are renowned for their health benefits. When it comes to their dietary preferences, Ayam Cemani chickens are not picky eaters. Originating from Java, Indonesia, the Ayam Cemani is considered an exceptionally rare breed. This striking appearance has earned it the nickname “Lamborghini chicken.” This results in the chicken’s meat, feathers, and even bones appearing entirely black. The Ayam Cemani is highly valued due to a rare condition called fibromelanosis, which causes an excess of dark pigment. Not only is it the most expensive, but it also possesses exceptional qualities that make it truly unique. When discussing costly chicken breeds, one breed stands out: the Ayam Cemani. ![]() |
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